magazinelogo

OAJRC Material Science

ISSN Print: Downloads: 8367 Total View: 96189
Frequency: Instant publication ISSN Online: 2632-2072 CODEN: OMSAAO
Email: oajrcms@hillpublish.com

Volumes & Issues

Current Issue

Article Open Access http://dx.doi.org/10.26855/oajrcms.2024.06.003

Preparation and Properties of Rare Earth Polymer Complex Photoconversion Ecological Agricultural Film Materials

Hongwei Di*, Nan Zhang, Chao Fan, Hua He, Junling Dong

Ningxia Normal University, Guyuan, Ningxia, China.

*Corresponding author:Hongwei Di

Published: July 16,2024

Abstract

Rare earth polymer complexes not only have excellent luminescence properties of rare earth metals but also have excellent mechanical properties of polymers, which are widely used in photochemistry, electrochemistry, aerospace, material dyeing, agricultural planting, and other aspects. With the in-depth study of rare earth polymer complexes, people have tried a variety of synthetic processes with different advantages, such as the synthesis of single rare earth polymer, the synthesis of double rare earth polymer, and the synthesis of rare earth double ligand polymer. In this study, the polymeric intermediate PBS(HDI)-DAC was prepared by doping β-diketol hydroxyl molecules and butanediol succinic acid esters with extended chain synthesis, and then the rare earth polymer complex Eu3+-PBS(HDI)-DAC was synthesized by hydrothermal method with rare earth element ion Eu3+. Finally, rare earth polymeric complex film Eu3+-PBS(HDI)-DAC was prepared by the light transfer agent. The rare earth polymer complex Eu3+-PBS(HDI)-DAC was characterized by FTIR, UV absorption, and fluorescence emission. The film was prepared by volatilization of solution and its mechanical properties were tested. Rare earth polymer complexes have good mechanical properties and have certain shielding and conversion abilities to ultraviolet light.

References

[1] Cardoso M A, Correia S F H, Frias A R, et al. Solar spectral conversion based on plastic films of lanthanide-doped ionosilicas for photovoltaics: down-shifting layers and luminescent solar concentrators [J]. Journal of Rare Earths, 2020, 38(5): 531-538.

[2] Liu H, Chu T, Rao Z, et al. The Tunable White‐Light and Multicolor Emission in An Electrodeposited Thin Film of Mixed Lanthanide Coordination Polymers [J]. Advanced Optical Materials, 2015, 3(11): 1545-1550.

[3] Tang H, Pu Z, Wei J, et al. Fluorescence-color-tunable and transparent polyarylene ether nitrile films with high thermal stability and mechanical strength based on polymeric rare-earth complexes for roll-up displays [J]. Materials Letters, 2013, 91: 235-238.

[4] Krishna Rao K S V, Liu H G, Lee Y I. Fluorescence spectroscopy of polymer systems doped with rare-earth metal ions and their complexes [J]. Applied Spectroscopy Reviews, 2010, 45(6): 409-446.

[5] Chen Z, Yin G. Suitability of a rare earth organic light conversion agent of Eu (III) complex to improve ultraviolet protection properties of cotton fabrics [J]. Textile Research Journal, 2010, 80(18): 1982-1989.

[6] Garcia-Torres J, Bosch-Jimenez P, Torralba-Calleja E, et al. Highly efficient luminescent materials: influence of the matrix on the photophysical properties of Eu (III) complex/polymer hybrids [J]. Journal of Photochemistry and Photobiology A: Chemistry, 2014, 283: 8-16.

[7] Liu D, Yu H, Wang Z, et al. Synthesis and fluorescence properties of novel 1, 10-phenanthroline-functionalized polyaryletherketone and its rare earth complexes [J]. Polymer International, 2010, 59(7): 937-944.

[8] Assunção I P, Costa I F, Santos P R S, et al. Luminescent analysis of Eu3+ and Tb3+ flufenamate complexes doped in PMMA polymer: Unexpected terbium green emission under sunlight exposure [J]. ACS Applied Optical Materials, 2022, 1(1): 354-366.

[9] Zou Q, Chen F, Peng G, et al. Luminescent properties of Eu (III) complexes with carboxylate ligands and their light conversion films [J]. Journal of Luminescence, 2023, 264: 120194.

[10] Znajdek K, Szczecińska N, Sibiński M, et al. Luminescent layers based on rare earth elements for thin-film flexible solar cells applications [J]. Optik, 2018, 165: 200-209.

[11] Zhang D, Gao B, Li Y. Synthesis and luminescence properties of polymer–rare earth complexes containing salicylaldehyde-type bidentate Schiff base ligand [J]. Luminescence, 2017, 32(5): 855-865.

[12] Zhang A, Xu W, Chen R, et al. Program controlling the emission color of blend polymer phosphors containing Eu (III), Tb (III), Be (II) ions for WLEDs [J]. Optical Materials, 2019, 89: 250-260.

[13] Ding G, Tang F, Ding Z, et al. Synthesis and luminescent properties of Eu 3+ organic complex PVA encapsulation film [J]. Functional Materials Letters, 2022, 15(02): 2251015.

[14] Knyazev A A, Krupin A S, Galyametdinov Y G. Luminescence behavior of PMMA films doped with Tb (III) and Eu (III) complexes [J]. Journal of Luminescence, 2022, 242: 118609.

[15] Shahi P K, Singh A K, Rai S B, et al. Lanthanide complexes for temperature sensing, UV light detection, and laser applications [J]. Sensors and Actuators A: Physical, 2015, 222: 255-261.

[16] Li S, Zhou L, Zhang H. Investigation progresses of rare earth complexes as emitters or sensitizers in organic light-emitting diodes [J]. Light: Science & Applications, 2022, 11(1): 177.

[17] He J, He Y, Zhuang J, et al. Luminescence properties of Eu3+/CDs/PVA composite applied in light conversion film [J]. Optical Materials, 2016, 62: 458-464.

[18] Forster P, Lugao A, Brito H, et al. Calorimetric investigations of luminescent films polycarbonate (PC) doped with europium complex [Eu (TTA) 3 (H 2 O) 2] [J]. Journal of Thermal Analysis and Calorimetry, 2009, 97(2): 497-502.

How to cite this paper

Preparation and Properties of Rare Earth Polymer Complex Photoconversion Ecological Agricultural Film Materials

How to cite this paper: Hongwei Di, Nan Zhang, Chao Fan, Hua He, Junling Dong. (2024) Preparation and Properties of Rare Earth Polymer Complex Photoconversion Ecological Agricultural Film MaterialsOAJRC Material Science6(1), 19-24.

DOI: http://dx.doi.org/10.26855/oajrcms.2024.06.003